國家衛生研究院 NHRI:Item 3990099045/9816
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    題名: Total synthesis of the naturally occurring glycosylflavone aciculatin
    作者: Yao, CH;Tsai, CH;Lee, JC
    貢獻者: Institute of Biotechnology and Pharmaceutical Research
    摘要: The new flavone-glycoside aciculatin (1), from Chrysopogon aciculatus, has been shown to have cytotoxic, anti-inflammatory, and antiarthritis activity. Further biological studies have been limited because of the limited availability of 1 from natural sources. Herein the first total synthesis of 1 in an overall yield of 8.3% is described. The synthesis involved the regio- and stereoselective glycosylation-Fries-type O-to-C rearrangement to construct the C-aryl glycosidic linkage, followed by a Baker-Venkataraman rearrangement and cyclodehydration to form the flavone scaffold.
    日期: 2016-07
    關聯: Journal of Natural Products. 2016 Jul;79(7):1719-1723.
    Link to: http://dx.doi.org/10.1021/acs.jnatprod.5b01051
    JIF/Ranking 2023: http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=NHRI&SrcApp=NHRI_IR&KeyISSN=0163-3864&DestApp=IC2JCR
    Cited Times(WOS): https://www.webofscience.com/wos/woscc/full-record/WOS:000380422400002
    Cited Times(Scopus): http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84979590898
    顯示於類別:[李靜琪] 期刊論文

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