國家衛生研究院 NHRI:Item 3990099045/1136
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    題名: Lithium naphthalenide induced reductive selenenylation of alpha-cyano ketones: A regiocontrolled process for alpha-phenylseleno ketones and one-pot conversion into enone system
    作者: Zhu, JL;Ko, YC;Kuo, CW;Shia, KS
    貢獻者: Division of Biotechnology and Pharmaceutical Research
    摘要: An efficient procedure for the regiocontrolled synthesis of a-phenylseleno ketones has been developed, making use of the lithium naphthalenide induced reductive selenenylation of the alpha-cyano ketone system as a key operation. Moreover, seleno ketones thus generated in situ, upon subsequent treatment with hydrogen peroxide and acetic acid, could be further converted into the corresponding enones with a high degree of regioselectivity, presumably due to the lithium salt mediated selenoxide syn-elimination process.
    關鍵詞: Chemistry, Organic
    日期: 2007-05-16
    關聯: Synlett. 2007 May(8):1274-1278.
    Link to: http://dx.doi.org/10.1055/s-2007-977448
    JIF/Ranking 2023: http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=NHRI&SrcApp=NHRI_IR&KeyISSN=0936-5214&DestApp=IC2JCR
    Cited Times(WOS): https://www.webofscience.com/wos/woscc/full-record/WOS:000247217700021
    Cited Times(Scopus): http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=34249784824
    顯示於類別:[夏克山] 期刊論文

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