國家衛生研究院 NHRI:Item 3990099045/8235
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    题名: Manganese(III)-catalyzed oxidative cyclization of aryl 1-cyanoalk-5-ynyl ketone systems: A convenient and general approach to cyclopenta[b]naphthalene derivatives
    作者: Wong, YC;Kao, TT;Huang, JK;Jhang, YW;Chou, MC;Shia, KS
    贡献者: Institute of Biotechnology and Pharmaceutical Research
    摘要: A convenient and general approach for cyclopenta[b]naphthalene derivatives containing a structurally diverse functionality at C-4 position has been successfully developed, whereby manganese(III) acetate plays a key role to facilitate the tandem 5-exo-dig and 6-exo/endo cyclization in an efficient manner. Various functional groups, including trimethyl silyl, aryl, ester, ketone, secondary/tertiary amide, phosphonate and halogen, capped on the terminal acetylenic unit are well tolerated under optimal reaction conditions. It is highly conceivable that this novel [6.6.5] framework formation procedure may have broad synthetic utility in light of its operational simplicity and high yields.
    日期: 2014-10
    關聯: Advanced Synthesis and Catalysis. 2014 Oct;356(14-15):3025-3038.
    Link to: http://dx.doi.org/10.1002/adsc.201400257
    JIF/Ranking 2023: http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=NHRI&SrcApp=NHRI_IR&KeyISSN=1615-4150&DestApp=IC2JCR
    Cited Times(WOS): https://www.webofscience.com/wos/woscc/full-record/WOS:000342906100019
    Cited Times(Scopus): http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84907811157
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