國家衛生研究院 NHRI:Item 3990099045/6642
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    题名: Chemical auxiliary-free polymerization yielding non-linear PEG for protein-resistant application
    作者: Lin, FS;Chien, CT;Chiu, WC;Lin, SY;Tseng, FG;Hwu, Y;Yang, CS
    贡献者: Center for Nanomedicine Research
    摘要: Current polymerization methods require the use of initiators or catalysts as auxiliaries to produce free radicals and then facilitate the chain propagation. However, these residual auxiliaries may affect polymer functions and cause toxicity, therefore, a time-consuming purification process is essential. Recently, synchrotron light has been established for generation of radicals in water without catalysts and initiators for polymerization. In this study, we used intensive synchrotron light as a potential tool to synthesize non-linear polyethylene glycol (NLPEG) which exhibits excellent protein-resistant property as compared to linear PEG (LPEG) on the surface. This novel synthesis concept provides an opportunity to produce NLPEG in a very short time (5 min) without employing various chemicals (pollutants) and with minimum environmental concern.
    日期: 2012-06
    關聯: RSC Advances. 2012 Jun;2(18):7174-7179.
    Link to: http://dx.doi.org/10.1039/C2RA20117H
    JIF/Ranking 2023: http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=NHRI&SrcApp=NHRI_IR&KeyISSN=2046-2069&DestApp=IC2JCR
    Cited Times(WOS): https://www.webofscience.com/wos/woscc/full-record/WOS:000306946500025
    Cited Times(Scopus): http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84864493030
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