國家衛生研究院 NHRI:Item 3990099045/5717

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Title:	Unraveling the photoluminescence puzzle of PAMAM dendrimers
Authors:	Lin, SY;Wu, TH;Jao, YC;Liu, CP;Lin, HY;Lo, LW;Yang, CS
Contributors:	Center for Nanomedicine Research;Division of Medical Engineering Research
Abstract:	The origin of poly(amidoamine) (PAMAM) photoluminescence was first established from the formation of unsaturated hydroxylamine, resulting from a cascade of Cope elimination reactions. The tertiary amines of the dendritic core of PAMAM are oxidized by H2O2 to form the amine oxide, which can subsequently induce elimination reactions through a cyclic transition state to generate an unsaturated hydroxylamine species with strong photoluminescence (see scheme).
Date:	2011-06-20
Relation:	Chemistry-A European Journal. 2011 Jun 20;17(26):7158-7161.
Link to:	http://dx.doi.org/10.1002/chem.201100620
JIF/Ranking 2023:	http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=NHRI&SrcApp=NHRI_IR&KeyISSN=0947-6539&DestApp=IC2JCR
Cited Times(WOS):	https://www.webofscience.com/wos/woscc/full-record/WOS:000292208900003
Cited Times(Scopus):	http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=79958797642
Appears in Collections:	[Chung-Shi Yang] Periodical Articles [Shu-Yi Lin] Periodical Articles [Leu-Wei Lo] Periodical Articles

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