國家衛生研究院 NHRI:Item 3990099045/3798

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Title:	Polyene cyclization promoted by the cross-conjugated alpha-carbalkoxy cyclohexenone system. An unusual 1,2-hydride shift under lewis acid catalysis
Authors:	Hsieh, MT;Chou, HH;Liu, HJ;Wu, HM;Ly, TW;Wu, YK;Shia, KS
Contributors:	Division of Biotechnology and Pharmaceutical Research
Abstract:	Polyene cyclization of the titled compounds under catalysis with AICI 3/SnCI4 gave rise to the corresponding polycycllc products, many of which were structurally highly unexpected, and thus, Individual X-ray analysis was required to finalize the structural Identification. Mechanistically, an unusual 1,2-hydride shift is proposed to elucidate the product formation.
Date:	2009-04-16
Relation:	Organic Letters. 2009 Apr 16;11(8):1673-1675.
Link to:	http://dx.doi.org/10.1021/ol802878t
JIF/Ranking 2023:	http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=NHRI&SrcApp=NHRI_IR&KeyISSN=1523-7060&DestApp=IC2JCR
Cited Times(WOS):	https://www.webofscience.com/wos/woscc/full-record/WOS:000265084300001
Cited Times(Scopus):	http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=65249085747
Appears in Collections:	[Kak-Shan Shia] Periodical Articles

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