國家衛生研究院 NHRI:Item 3990099045/15003

NHRI > Institute of Biomedical Engineering and Nanomedicine > Chia-Wen Wu > Periodical Articles > Item 3990099045/15003

Please use this identifier to cite or link to this item: http://ir.nhri.org.tw/handle/3990099045/15003

Title:	Continuous and ultrafast MOF synthesis using droplet microfluidic nanoarchitectonics
Authors:	Wu, HY;Wu, CL;Liao, WS;Matsagar, BM;Chang, KY;Huang, JH;Wu, KCW
Contributors:	Institute of Biomedical Engineering and Nanomedicine
Abstract:	Metal-organic frameworks (MOFs) constitute a class of porous materials with widespread applications owing to their remarkable and tunable properties. Although MOFs are currently the leading examples of porous materials, they are yet to demonstrate promising progress in industrial applications due to limitations in the current production processes, such as the requirement of excess solvent, intensive labor requirements, and long processing times. Herein, we propose a continuous droplet microfluidic system to accelerate the generation of MOFs and to achieve scalable continuous production. The results demonstrate the formation of uniform MOFs within 3 min using a microfluidic system, which is much faster than the conventional hydrothermal synthesis that requires 300 min. By precisely controlling the flow rates of the two phases, we enhanced productivity and generated minimum droplets to create a restricted microreactor. We also observed that the crystallinity of ZIF-8 and MIL-100 improved significantly with increasing synthesis temperature. We have also provided a de novo method for the one-pot synthesis of gold-encapsulated ZIF-8, overcoming the disadvantages of impregnation, precipitation, or ion exchange associated with metal immobilization on MOFs. Overall, the novel microfluidic system proposed herein achieves rapid and scalable continuous production of MOFs under mild conditions.
Date:	2023-03-22
Relation:	Journal of Materials Chemistry A. 2023 Mar 22;11:9427-9435.
Link to:	http://dx.doi.org/10.1039/d2ta09932b
JIF/Ranking 2023:	http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=NHRI&SrcApp=NHRI_IR&KeyISSN=2050-7488&DestApp=IC2JCR
Cited Times(WOS):	https://www.webofscience.com/wos/woscc/full-record/WOS:000962350200001
Cited Times(Scopus):	https://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85152116757
Appears in Collections:	[Chia-Wen Wu] Periodical Articles

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